It is not available for Standard and Basic tiers on DTU-model. You will not find this feature available on S4. Only premium tiers on DTU model have available the zone redundant feature. That feature is free of additional charges on Premium tiers.
Why is free? With the introduction of Azure Availability Zones, SQL Database can place different replicas of the Premium database to different availability zones in the same region. To eliminate a single point of failure, the control ring is also duplicated across multiple zones as three gateway rings (GW). The routing to a specific gateway ring is controlled by Azure Traffic Manager (ATM). Because the zone-redundant configuration in the Premium (DTU model) service tiers does not create additional database redundancy, you can enable it at no extra cost