Hello Hopper. To change your default Outlook calendar to an imported calendar, you'll need to make the data file that a calendar is associated with the default data file. Outlook makes the link from a default calendar to a default data file, not to a calendar folder. Go to it's File > Info > Account Settings > Account Settings, then select the data file that your imported calendar (such as a PST) is associated with under the Data Files tab and click Set as Default. Close and restart Outlook so that the change is made.
Making the data file default means when you create new events or receive meeting invites, they will be saved to the calendar that is associated with that data file. If your imported calendar is simply a sub-folder in your main account Outlook will not allow you to set it as default and you will need to manually move the events to it.
Here's the reference: Set default calendar
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