That depends on whether you're using a Microsoft account or a local account.
Your username is tied to your Microsoft account name. To change it:
- Go to the Microsoft Account Page: https://account.microsoft.com
- Sign in and navigate to Your Info.
- Click Edit Name, update your first and last name, complete the CAPTCHA, and click Save.
- Restart your Surface Pro to apply the changes.
Note that your old under c:\Users will not be changed.
if Your account is Local You can change the display name using either the Control Panel or Local Users and Groups.